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Microcontroller choice

I want to make a bms home system with 8051.But i don't know wich microcontrollers to use.To be specific i need
a: 1 microcontroller that can communicate with wifi because i want to control the entire system via my pc
b:unknown number of microcontrollers which they were connect with the wifi microcontroller.Also in these microcontrollers will connect the d/a and a/d converters for the sensors.

*For this project will i need any other chips except controllers,converters and the "typical" max232, etc...?
*To make the network between all the controllers which protocol do you recommend?will i need specific controllers to make the netwrok?

plz help....
Thanx

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