I'm new and no experience.Can anyone help me please?
For Keil & Cortex-M specifically, Start here:
http://www2.keil.com/mdk5/learn
http://www.keil.com/support/man/docs/mdk_gs/
http://www.keil.com/support/man/docs/uv4/
http://www.keil.com/books/
For general microcontroller getting started tips:
https://www.avrfreaks.net/comment/2079906#comment-2079906